To address this specific gap, Vanadium Redox Flow Batteries (VRFBs) have emerged as a powerful and promising technology tailored for large-scale energy storage , . The defining characteristic of a VRFB is the unique decoupling of its power and energy capacity.
Furthermore, innovations in coordination chemistry are paving the way for new redox-active molecules that could potentially replace vanadium, addressing cost and supply chain concerns . By fine-tuning the redox reactions and electrolyte properties, significant improvements in battery efficiency and capacity are expected.
The mechanism unfolds through a sequence of events: As established, the permeability of vanadium ions through a typical CEM follows the order V 2+ > VO 2+ > VO 2+ > V 3+ . During operation, all four species cross the membrane in both directions, but the net flux is unbalanced.
This net transfer of vanadium from the anolyte to the catholyte leads to a gradual accumulation of the total moles of vanadium in the positive electrolyte tank and a corresponding depletion in the negative tank . This is often referred to as a stoichiometric or concentration imbalance.
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