However, over-discharge (OD), defined as a battery voltage falling below safe operating thresholds, poses significant risks to both performance and safety. This review analyzes intrinsic and extrinsic OD mechanisms.
Consequently, the battery discharges at a constant current of a reduced voltage value, thereby stabilizing the electrochemical reaction within the battery. This leads to the voltage curve gradually approaching a plateau, which is determined by the material and structural composition of the battery.
When the discharge rate is increased to 3C, the capacity decreases from 22.7 Ah to 18.6 Ah. Under OD conditions, the capacity decreased from 23 Ah to 20 Ah. Notably, the battery capacity drops dramatically by 7.79 % and 24.46 % when over-discharged to 0.5 V and 0.0 V, respectively, further weakening cycling capability.
The dissolution and rupture of the SEI membrane leads to an increase in impedance during deep discharge, which results in a decrease in battery capacity and significantly shortens battery life at lower discharge voltages. This indicates that batteries subjected to abusive discharge with lower cut-off voltages lose capacity more rapidly.
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